Analysis of the influence of the n-hexane content in the mixture with rapeseed oil on the auto-ignition delay angle of the fuel
More details
Hide details
1
Faculty of Mechanical Engineering
Department of Automotive Vehicles, Lublin University of Technology, Poland
These authors had equal contribution to this work
Submission date: 2025-06-20
Final revision date: 2025-09-11
Acceptance date: 2025-10-06
Online publication date: 2025-11-14
Corresponding author
Przemysław Sander
Faculty of Mechanical Engineering
Department of Automotive Vehicles, Lublin University of Technology, Nadbystrzycka 36D, 20-618, Lublin, Poland
KEYWORDS
TOPICS
ABSTRACT
Increasing emission-reduction requirements and EU renewable-energy targets have created a demand for biofuels that can be operated in diesel engines without modification. Current production routes—FAME and HVO—although markedly improving the physicochemical properties of rapeseed oil, are carried out in capital-intensive industrial plants and depend on continuous feedstock supply. To simplify the production chain, rapeseed oil was diluted with the inert hydrocarbon n-hexane; the resulting decrease in viscosity and flash point facilitated spray formation and ignition initiation. The effect of n-hexane content (v/v) in blends with rapeseed oil on the ignition-delay angle in a direct-injection diesel engine was analysed. Cylinder-pressure traces were used to determine the crank-angle interval between the start of injection and the start of combustion, and the results were compared with data for commercial diesel fuel and neat rapeseed oil. A progressive increase in the n-hexane fraction was found to shorten the ignition-delay angle relative to neat rapeseed oil, bringing it closer to the value observed for diesel fuel. The results confirm the suitability of the investigated blends as an alternative fuel and indicate that they can be used in currently operated diesel engines without costly modifications.
REFERENCES (36)
2.
Baczewski K, Kałdoński T. Paliwa do silników o zapłonie samoczynnym. WKŁ. Warszawa 2008.
3.
Bayindirli C. Celik M. Investigation of combustion and emission characteristics of n-hexane and n-hexadecane additives in diesel fuel. J Mech Sci Tech. 2019;33:1937-1946.
https://doi.org/10.1007/s12206....
4.
Cheng C, Faurskov Cordtz R, Dyhr Pedersen T, Winther K, Langballe Førby N, Schramm J. Investiga-tion of combustion characteristics, physical and chemical ignition delay of methanol fuel in a heavy-duty turbo-charged compression ignition engine. Fuel. 2023;348:128536.
https://doi.org/10.1016/j.fuel....
5.
Cisek J, Borowski A, Całkowska J, Wichary Ł. Effect of nitrON® cetane-detergent additive to B7 fuel on energy parameters and exhaust gas composition of a 6Dg locomotive with a Caterpillar C27 engine. Combustion Engines. 2021;186(3):51-58.
https://doi.org/10.19206/CE-14....
6.
Crua C, Kennaird DA, Sazhin SS, Heikai MR, Gold MR. Diesel autoignition at elevated in-cylinder pressures. Int J Engine Res. 2004;5(4):365-374.
https://doi.org/10.1243/146808....
7.
Górski K, Sander P, Longwic R. The assessment of ecological parameters of diesel engine supplied with mixtures of canola oil with n-hexane. IOP Conf Ser Mater Sci Eng. 2018; 421 (4):042025.
https://doi.org/10.1088/1757-8....
8.
Hardenberg HO, Hase FW. An empirical formula for computing the pressure rise delay of a fuel from its cetane number and from the relevant parameters of direct-injection diesel engines. SAE Technical Paper. 790493. 1979.
https://doi.org/10.4271/790493.
9.
Hardenberg HO, Hase FW. Empirical formula for computing the pressure rise delay of a fuel from its cetane number and from the relevant parameters of direct-injection diesel engines. SAE Preprint 1979.
11.
Jaroń A, Borucka A, Sobecki G. Assessment of the possibility of using nanomaterials as fuel additives in combustion engines. Combustion Engines. 2022;189.
https://doi.org/10.19206/CE-14....
12.
Jo S, Park S, Kim HJ, Lee JT. Combustion improvement and emission reduction through control of ethanol ratio and intake air temperature in reactivity controlled compression ignition combustion engine. Appl Energy. 2019;250:1418-1431.
https://doi.org/10.1016/j.apen....
13.
Kowalewicz A. Application of biofuels to compression ignition engines. Mech Mech Eng. 2005;9:69-90.
14.
Kowalewicz A, Lotko W. Alternative fuels for automotive I.C. engines and some results of application to S.I. and C.I. engine. Proceedings of the Third Asia-Pacific International Symposium on Combustion and Energy Utilization n.d.. 2005;1.
https://doi.org/10.1243/095440....
15.
Kryshtopa S, Górski K, Longwic R, Smigins R, Kryshtopa L. Increasing parameters of diesel engines by their transformation for methanol conversion products. Energies. 2021;14(6):1710.
https://doi.org/10.3390/en1406....
16.
Krzemiński A, Jaworski A, Kuszewski H, Woś P. A comparative study on selected physical properties of diesel–ethanol–dodecanol blends. Combustion Engines. 2024;196(1):99-105.
https://doi.org/10.19206/CE-17....
18.
Longwic R, Sander P. The characteristics of the combustion process occurring under real operating conditions of traction. IOP Conf Ser Mater Sci Eng. 2016;148:012071.
https://doi.org/10.1088/1757-8....
19.
Longwic R, Sander P, Jańczuk B, Zdziennicka A, Szymczyk K. Modification of canola oil physicochemical properties by hexane and ethanol with regards of its application in diesel engine. Energies. 2021;14(15):4469.
https://doi.org/10.3390/en1415....
20.
Longwic R, Sander P, Lotko W, Gorski K, Janczuk B, Zdziennicka A et al. Self-ignition of rapeseed and n-hexane mixtures in diesel engine. Przem Chem. 2020;99:206-210.
https://doi.org/doi.org/10.151....
21.
Longwic R, Sander P, Zdziennicka A, Szymczyk K, Jańczuk B. Combustion process of canola oil and n-hexane mixtures in dynamic diesel engine operating conditions. Appl Sci. 2020;421(4):042025.
https://doi.org/10.3390/app100....
22.
Lotko W. Studium zastosowań paliw alternatywnych do silników o zapłonie samoczynnym. Radom 1999.
23.
Lotko W. Self-ignition delay and control parameters of diesel engines for different vehicle feeding systems and different fuels. Adv Sci Technol Res J. 2021;15(1):245-254.
https://doi.org/10.12913/22998....
25.
Mohammed O, Suleiman E. The history of the internal combustion engine. Annuls of the Faculty of Engineeeing Hunedoara. 2017;3.
26.
Pirouzfar V, Zarringhalam Moghaddam A, Mirza B. Physicochemical properties and combustion performance of gas oil-fuel additives. J Energy Resour Technol. 2012;134(4):041101.
https://doi.org/10.1115/1.4007....
27.
Polska norma PN-EN 590:2013. n.d.
28.
Raţiu S. The history of the internal combustion engine. Annals of the Faculty of Engineering Hunedoara. 2003;3.
29.
Rosseel E, Sierens R. The physical and the chemical part of the ignition delay in diesel engines. SAE Technical Paper. 961123. 1996.
https://doi.org/10.4271/961123.
30.
Singh AP, Mustafi NN, Sharma YC, Agarwal AK. Introduction to alternative fuels and their utilization strategies in internal combustion engines. Energy, Environment, and Sustainability. 2020.
https://doi.org/10.1007/978-98....
31.
Sun B, Zhao S, Zhai Y, Liu Q, Wu G, Wu H. Effect of fuel physicochemical properties on spray and particulate emissions. ACS Omega. 2022;7(48):44251-44265.
https://doi.org/10.1021/acsome....
32.
Wajand JA, Wajand JT. Tłokowe silniki spalinowe średnio i szybkoobrotowe. Warszawa: WNT 2005.
33.
Zabłocki M. Wtrysk i spalanie w silnikach wysokoprężnych. Wydawnictwo Komunikacji i Łączności. Warszawa 1976.
34.
Zaharin MSM, Abdullah NR, Najafi G, Sharudin H, Yusaf T. Effects of physicochemical properties of biodiesel fuel blends with alcohol on diesel engine performance and exhaust emissions: a review. Renew Sustain Energy Rev. 2017;79:475-493.
https://doi.org/10.1016/j.rser....
35.
Zdziennicka A, Szymczyk K, Jańczuk B, Longwic R, Sander P. Adhesion of canola and diesel oils to some parts of diesel engine in the light of surface tension components and parameters of these substrates. Int J Adhes Adhes. 2015;60:23-30.
https://doi.org/10.1016/j.ijad....
36.
Zdziennicka A, Szymczyk K, Jańczuk B, Longwic R, Sander P. Surface, volumetric, and wetting properties of oleic, linoleic, and linolenic acids with regards to application of canola oil in diesel engines. Appl Sci. 2019;9(17):3445.
https://doi.org/10.3390/app917....